![]() waterproof watch case.
专利摘要:
The invention relates to a waterproof watch case comprising two elements respectively forming a middle part (2) and a bottom, a seal being interposed between these two elements, a first of these elements comprising a first portion of peripheral side wall against the second element also having a second undercut peripheral peripheral wall portion which extends in height and which is of complementary shape to the first peripheral sidewall portion of the first element; first and second peripheral side wall portions of the first and second members being arranged such that, in a first angular position with respect to a pivot axis called closure axis (O-O'), the first element can be dissociated from the second element and that in a second angular position in which the first element is t rotated by a predetermined angle about said closure axis (O-O') from the first position, the first member is locked in the second member by compressing the packer, the sealed watch case being characterized by that the bottom and the middle part (2) are made of a material whose hardness is at least 1000 HV. 公开号:CH710878A2 申请号:CH00367/15 申请日:2015-03-17 公开日:2016-09-30 发明作者:Silvant Olivier 申请人:Omega Sa; IPC主号:
专利说明:
Technical field of the invention The present invention generally relates to watch cases and more particularly a waterproof watch case including a middle and a bottom that can engage and lock in the middle part by printing at the bottom a rotational movement of an angle determined around a geometric axis which will be called closure axis in the following description. Technological background of the invention A watch case meeting this definition is already described in document CH 338 405. In this document, the watch case comprises a middle part, a bottom and a seal interposed between the bottom and the middle part. The bottom has a peripheral flange having an inclined outer wall shaped ellipse or polygon and the middle part has an annular groove having an inclined wall of a shape corresponding to that of the wall of the bottom flange. The rim of the bottom can thus be engaged in the groove of the middle part and be locked in this groove by rotating the bottom relative to the middle part. This box of the prior art has the disadvantage of wearing quickly. Indeed, because of the elliptical or polygonal shape of the peripheral rim of the bottom and the complementary shape of the groove of the middle part, the bottom can be locked on the middle part only according to lines of contact which extend in one direction tangent to the inclined wall of the flange or groove. This results in a sealed closure of the box is no longer provided efficiently, or even more assured at all, after a number of cycles of opening and closing the bottom. [0004] To this is added the fact that, in a watch case of this type, the compression behavior of the seal is similar to that of a seal of a watch case in which the bottom is attached to the middle part by screws. In such watch cases, the seal is compressed strongly in the areas where the screws are located, and very weakly between these areas, which leads to sealing problems. However, in the case of a watch case of the type described in document CH 338 405, when tightening the bottom on the caseband, only those parts of the bottom which, thanks to the intrinsic flexibility of the bottom, come into contact with the middle part tend to penetrate the middle part and to compress the joint in these zones of contact. Thus, the areas of high and low compression succeed each other along the seal, which poses sealing problems. The document FR 1 359 524 describes a waterproof watch case comprising an external element and an internal element, namely a bottom and a middle part engaged one inside the other. A seal carried by one of these elements is pressed axially against a shoulder of the other. The outer member is provided with internal projections distributed around its periphery, while the inner member has external projections also distributed around its periphery and engaged on the internal projections to fix the outer and inner elements to each other. The projections of these inner and outer members are axially limited by generator surfaces perpendicular to the axis of the box, each of these surfaces forming a ramp on which a projection of one of the elements can engage to cause a displacement axial axis of the other element when the projections of the latter are engaged on said ramps. Such a watch case has the particular disadvantage of being complicated to achieve and is therefore a high cost. [0006] A waterproof watch case intended to remedy the problems mentioned above has already been disclosed in document CH 685 526. Such a watch case includes in particular a bottom and a caseband both made of steel. Steel is a material commonly used in the field of watchmaking, in particular because it is easy to machine because of its hardness which does not usually exceed 200 to 300 HV. In addition, steel is a solid material. Finally, the steel is ductile, which allows the bottom and the middle part to deform and their opposite surfaces to marry when the bottom is tightened on the middle part, the resulting clamping force thus being excellent. Steel, however, has some disadvantages. The designers are limited in particular in terms of shapes that can be given to the various components of the watch case as well as in terms of choice of colors. Summary of the invention The invention aims to overcome the disadvantages of the aforementioned prior art as well as others by providing a waterproof watch case made of a material offering manufacturers a great freedom of choice of shapes and shapes. colors. For this purpose, the invention relates to a sealed watch case having two elements respectively forming a middle and a bottom, a seal being interposed between these two elements, a first of these elements comprising a portion of an axially delimited and an undercut peripheral side wall, the second member also having an axially delimited peripheral sidewall portion and an undercut of complementary shape to the sidewall portion of the first member, the sidewall portions of the first and second elements being arranged so that, in a first angular position with respect to a pivot axis called closure axis, the first element can be dissociated from the second element and that, in a second angular position in which the first element is rotated a predetermined angle about said closure axis from the first position, the first element is locked in the second element by compressing the lining, the sealed watch case being characterized in that the bottom and the middle part are made of a material whose hardness is at least 1000 HV. According to a complementary feature of the invention, the material in which the bottom and the middle are made is a ceramic. According to a particular embodiment of the invention, the bottom and the middle are made of sintered zirconia oxide. With these features, the present invention provides a waterproof watch case in which the bottom and the middle part are made of a material whose hardness is at least 1000 HV. Materials that meet this definition include ceramics, for example sintered zirconia. It is known that such ceramics offer great possibilities in terms of shapes and choice of colors. Nevertheless, the substitution of steel by ceramics was not without difficulty. Indeed, ceramics are extremely hard and fragile materials. The skilled person was therefore of the opinion that the very low ductility of the ceramic materials would not allow a corresponding bottom and middle made of such a material to deform sufficiently so that their facing surfaces can marry properly when the bottom is tight on the middle to ensure a sufficient resultant clamping force. On the other hand, the skilled person also feared that the thin nets whose machining is made necessary by the watch cases of the type of object of the present patent application would be too fragile and could break due to fragility. ceramic materials. All concurred therefore to divert the skilled person from the choice of a hard material for the realization of the components of a waterproof watch case according to the invention. Now, to his surprise, the Applicant has found, after several attempts, that the prejudices of the person skilled in the art were unfounded and that components, bottoms and frames, for waterproof watch cases could be made of ceramic and present all the required guarantees, particularly in terms of clamping force and mechanical strength. In addition, thanks to the choice of materials of great hardness such as ceramics, designers enjoy great freedom both in terms of choice of shapes than colors. The peripheral side wall portion of the first element comprises at least two circular arc sections each centered on a point offset from the closure axis, these two sections being connected to one another by a section returning to form projections. The peripheral side wall portion of the second element comprises, for its part, at least two arcuate segments each centered on a point offset from the closure axis, these two sections being connected to each other by a section whose profile is broken and which defines a clearance depth such that it allows, in the first angular position, the passage of the projections of the first element in the clearances of the second element. Each arcuate section of the first element is associated with an arcuate section of the second element, the sections associated with each other having substantially the same radius so that, in the first angular position, each section arc of the first element is eccentric relative to the arcuate section of the second element associated with it, while in the second angular position, each arcuate section of the first element is concentric to the arcuate section of the second element associated with it. Thus, the side wall of each arcuate section of the second element is in intimate contact throughout its entire extent with the side wall of the arcuate section of the first element associated therewith. The contact between the peripheral side wall portion of the first element and the peripheral side wall portion of the second element is therefore a larger surface area. The friction forces between these two elements are therefore better distributed, which improves the reliability of the system and reduce wear. The structure of the box according to the invention also allows to obtain a progressive tightening of the first element on the second element by compressing the seal uniformly and progressively. Preferably, the peripheral side wall portion of the first and second elements comprises four sections arcuate regularly distributed along the perimeter of the first and second elements. Thus, the bottom is self-centering on the middle part, so that its positioning on the middle part before blocking is facilitated. Preferably, the first element is the bottom and the second element is the middle part. Advantageously, the peripheral sidewall portion of the bottom is located at the outermost relative to the peripheral sidewall portion of the middle part. Brief description of the figures Other features and advantages of the present invention will emerge more clearly from the reading of the detailed description which follows of an exemplary embodiment of a sealed watch case according to the invention, this example being given purely by way of illustrative and not limiting only in connection with the accompanying drawing in which:<tb> Figs. 1 and 2 <SEP> are respectively bottom plan and top plan views of the middle and only the bottom, some dimensions having been exaggerated;<tb> fig. 3 <SEP> is a plan view from below of the box on which the bottom, represented in phantom, is engaged on the middle part but is not blocked thereon;<tb> fig. 4 <SEP> is a view similar to that of FIG. 3, the bottom being engaged on the middle and locked on it;<tb> fig. 5 <SEP> is a partial sectional view taken along line V-V of FIG. 3, and<tb> fig. 6 <SEP> is a partial sectional view taken along line VI-VI of FIG. 4. Detailed description of an embodiment of the invention Referring in particular to FIGS. 5 and 6 appended to the present patent application, the sealed watch case according to the invention, designated as a whole by the general numerical reference 1, comprises in particular two elements respectively forming a middle part 2 of generally circular shape and a bottom 4 of also circular form. The middle 2 is provided with two pairs of horns 6. According to the invention, the bottom 4 and the middle part 2 are made of a material whose hardness is at least 1000 HV. A preferred example of a material having a hardness of at least 1000 HV is a ceramic, particularly a sintered zirconia. Thanks to these features, the present invention provides a waterproof watch case in which the bottom and the middle part are made of a material whose hardness is at least 1000 HV. Materials that meet this definition include ceramics, for example sintered zirconia. It is known that such ceramics offer great possibilities in terms of shapes and choice of colors. Nevertheless, the substitution of steel by ceramics was not without difficulty. Indeed, ceramics are extremely hard and fragile materials. The skilled person was therefore of the opinion that the very low ductility of the ceramic materials would not allow a bottom and a corresponding middle made in such a material to deform sufficiently so that their facing surfaces can s' fit properly when the bottom is tight on the middle to ensure sufficient resultant clamping force. On the other hand, the skilled person also feared that the thin nets whose machining is made necessary by the watch cases of the type of object of the present patent application would be too fragile and could break due to fragility. ceramic materials. All concurred thus to divert the skilled person from the choice of a hard material for the realization of the components of a waterproof watch case according to the invention. Now, to his surprise, the Applicant has found, after several attempts, that the prejudices of the person skilled in the art were unfounded and that components, bottoms and frames, for waterproof watch cases could be made of ceramic and present all the required guarantees, particularly in terms of clamping force and mechanical strength. In addition, thanks to the choice of materials of great hardness such as ceramics, designers enjoy great freedom both in terms of choice of shapes than colors. According to a complementary feature of the invention, the bottom 4 comprises an annular peripheral shoulder 8 which receives a seal 10 intended to be compressed between a first bearing surface 12 of the annular peripheral shoulder 8 and a lower face. 14 of the middle part 2. This arrangement makes it possible to avoid having to machine an annular groove in the lower face 14 of the caseband 2, an operation made difficult because of the hardness of the middle part 2 and the diameter of this annular groove, necessarily more small as the diameter of the bottom 4. The annular peripheral shoulder 8 is extended radially outwards in the manner of a stair step by an annular flange 16 delimited internally by a first peripheral side wall portion 20. This first portion of the peripheral side wall 20 extends in height between two planes P1 and P2 which are materialized respectively by the first bearing surface 12 of the annular peripheral shoulder 8 and by a second bearing surface 22 of the annular flange 16. In the example shown in the drawing, the first peripheral side wall portion 20 is undercut, that is to say it is slightly inclined relative to a closure axis O-O which, in the example shown, is confused with the geometric axis of the waterproof watch case 1, that is to say the axis parallel to the axis of rotation of the needles. Preferably, the angle of inclination of the first peripheral side wall portion 20 is of the order of 10 °. The inner face or surround 24 of the middle part 2 comprises, in its part adjacent to the lower face 14, a second peripheral side wall portion 26 forming a groove 28 open towards the inside. This second peripheral side wall portion 26, also undercut, is delimited in height by two planes P3 and P4 which are respectively materialized by a third and a fourth bearing surfaces 30 and 18 of the groove 28. The profile of the second peripheral side wall portion 26 of the middle part 2 is complementary to that of the first peripheral side wall portion 20 of the bottom 4. In other words, the inclination of the second peripheral side wall portion 26 is substantially equal to that of the first peripheral side wall portion 20 of the bottom 4. Concerning the inclination of the first and second peripheral side wall portions 20 and 26, it will finally be noted that their conicity is, in the illustrated example, directed in the direction of the bottom 4. It will be understood that the first and second peripheral side wall portions 20 and 26 of the bottom 4 and the middle part 2 are arranged so that, in a first angular position of the bottom 4 with respect to the axis O-O (FIG 3), the bottom 4 can be separated from the middle part 2 and, in a second angular position (FIG 4) in which the bottom 4 is rotated by a predetermined clearance angle Ω about the axis O -O from the first angular position, the bottom 4 is blocked on the middle part 2 by compressing the lining 10. Moreover, the height Hf corresponding to the distance between the planes P1 and P2 is less than the height Hc which corresponds to the distance separating the planes P3 and P4, so that the second bearing surface 22 of the annular flange 16 does not come into contact with the third bearing surface 30 of the groove 28 in the second angular position of the bottom 4 as defined above. Referring more particularly to FIGS. 1 to 4, it can be seen that the peripheral lateral wall portion 26 of the middle part 2 comprises four circular arcuate sections 32, two successive circular arcuate sections 32 each being connected to each other by a section reentrant 34 oriented substantially radially to form a projection 36. Each arcuate section 32 occupies a circular arc Ac close to 90 ° and is centered on a point Cc offset from the closure axis O-O which, in the particular example, is coincident with the axis of the caseband 2. In the example described and illustrated, the arcuate sections 32 have the same radius Rc, so that the centers Cc of each of these sections 32 are arranged on a circle 38 (shown in phantom) centered on the closing axis O-O. As mentioned in the previous paragraph, the arcuate sections 32 which form the peripheral side walls 26 of the middle part 2 are eccentric with respect to the closure axis O-O and the distance of their points relative to the axis O-O varies gradually when one traverses the arcuate sections 32 along their entire length. In the illustrated example, this distance increases when one traverses the arcuate sections 32 in the counterclockwise direction seen from below. The peripheral side wall portion 20 of the bottom 4 also comprises four circular arcuate sections 40 each centered on a point YJ offset from the geometric closure axis O-O. Each arcuate section 40 occupies a circular arc Af less than 90 °, for example about 80 °, and has the same radius Rf, so that the centers Cf of arcuate sections 40 are arranged on a circle 42 (shown in phantom) centered on the O-O closure axis. Each of the arcuate portions 40 of the bottom 4 is associated with an arcuate section 32 of the middle part 2, these arcuate sections 32, 40 associated with each other having substantially the same radius, of so that the circles 38 and 42 are merged. It will be noted that the value of the angle Δf corresponds substantially to the value of the angle Δf deduced from the clearance angle Ω. However, unlike the arcuate portions 32 of the middle part 2, two successive arcuate segments 40 of the bottom 4 are connected to each other by a broken profile portion 44 which defines a clearance 46 of depth such that it allows the passage of the projections 36 of the middle part 2 in the first angular position (Figure 3). The broken profile portion 44 comprises a first part 48 which extends from the end of an arcuate section 40 and approaches the closure axis O-O substantially to the right of the end of the next arcuate section 40 to join the latter by a second portion 50 extending substantially radially. Thus, thanks to the profile of the peripheral side wall portions 20 and 26 respectively of the bottom 4 and the middle part 2 of the invention and in particular the broken profile of the peripheral side wall 20 of the bottom 4, the flange 16 of the bottom 4 can, in the first angular position shown in FIG. 3, be engaged freely in the opening of the middle part 2, the sections 40 of the bottom 4 being at that time eccentric with respect to the sections 32 of the middle part 2 which correspond to them. It then suffices to turn the bottom 4 relative to the middle part 2 by a predetermined clearance angle Q from the first angular position to bring it into the second angular position (FIG 4) in which each section 40 of the bottom 4 is concentric with the section 32 of the middle part 2 which is associated with it to ensure the locking of the bottom 4 on the middle part 2. During this rotation which makes it possible to move the bottom 4 from its first angular position to its second angular position, the annular flange 16 of the bottom 4 penetrates progressively into the middle part 2, thereby causing compression of the seal 10 and bringing each section 40 of the bottom 4 into intimate contact over its entire surface with the section 32 of the caseband 2 which is associated, thus ensuring effective blocking of the bottom 4 on the middle part 2. The clearance angle Q is the minimum angle necessary to disengage the first peripheral side wall portion 20 of the second peripheral side wall portion 26 during the pivoting of the bottom 4 in the middle part 2. In the illustrated example this clearance angle is of the order of 20 °. Preferably, the clearance angle Q. will be as small as possible so that the contact surface between the first and second peripheral side wall portions 20 and 26 is as large as possible, so as to obtain a better blocking from the bottom 4 on the middle part 2. It will thus obtain a compression of the seal 10 over a larger part of its perimeter. Although in the embodiment of the invention which has just been described, the peripheral side wall portion 20 of the bottom 4 is external and the peripheral side wall portion 26 of the middle part 2 is internal, it Of course, according to an alternative embodiment, the opposite could be provided. In the latter case, a flange similar to the annular flange 16 is formed on the middle part 2 in place of the open groove 28 formed, in the example described above, by the peripheral side wall portion 26, and a similar groove the latter is formed in the bottom 4 instead of the annular rim 16. It is understood that other embodiments of the waterproof watch case according to the invention may still be envisaged. For example, there may be provided watch cases whose sidewall portions of the bottom and the middle have respectively two, three, five or more sections in an arc. In this case, the shape of the broken profile portion connecting the bottom sections can of course vary. While in the embodiment of the watch case described above all the arcuate portions of a peripheral sidewall portion of one or the other of the first and second elements, bottom or middle, have the same radius, we can predict that the arcuate sections of the first element have different radii and the arcuate sections of the other element have radii corresponding to those of the first element. It will be noted that the relative dimensions of the arcuate sections have deliberately been exaggerated to facilitate understanding of the invention. Nomenclature [0040]<tb> Waterproof Watch Box <SEP> 1<Tb> Build <September> 2<Tb> Background <September> 4<Tb> Horns <September> 6<tb> Annular Peripheral Shoulder <SEP> 8<tb> Gasket <SEP> 10<tb> First support surface <SEP> 12<tb> Bottom side <SEP> 14<tb> Ring flange <SEP> 16<tb> First portion of peripheral sidewall <SEP> 20<tb> Plans <SEP> P1 and P2<tb> Second support surface <SEP> 22<tb> Closing axis <SEP> O-O<tb> Internal face or entourage <SEP> 24<tb> Second portion of peripheral sidewall <SEP> 26<Tb> groove <September> 28<tb> Plans <SEP> P3 and P4<tb> Third support surface <SEP> 30<tb> Clearance Angle <SEP> Ω<Tb> Height <September> Hc<tb> Semicircular sections <SEP> 32<tb> Incoming section <SEP> 34<Tb> stud <September> 36<tb> Circular arc <SEP> Ac<Tb> point <September> Cc<Tb> Radius <September> Rc<Tb> Circle <September> 38<tb> Semicircular sections <SEP> 40<Tb> point <September> Cf<Tb> Circle <September> 42<tb> Broken Profile Portion 44 <SEP> 44<Tb> clearance <September> 46<tb> First part <SEP> 48<tb> Second part <SEP> 50
权利要求:
Claims (9) [1] 1. Watertight watch case comprising two elements respectively forming a middle part (2) and a bottom (4), a seal (10) being interposed between these two elements, a first of these elements comprising a first portion of side wall undercut device (20) which extends in height, the second element also having a second upstanding sidewall peripheral portion (26) which is of complementary shape to the first portion peripheral side wall (20) of the first member, the first and second peripheral side wall portions (20, 26) of the first and second members being arranged such that in a first angular position with respect to a pivot axis closure (O-O), the first element can be dissociated from the second element and that, in a second angular position in which the first element the element is rotated by a predetermined angle (O) about said closure axis (O-O) from the first position, the first element is locked in the second element by compressing the seal (10), the waterproof watch case being characterized in that the bottom (4) and the middle part (2) are made of a material whose hardness is at least 1000 HV. [2] 2. Sealed watch case according to claim 1, characterized in that the material in which are formed the bottom (4) and the middle part (2) is a ceramic. [3] 3. Sealed watch case according to claim 2, characterized in that the bottom (4) and the middle part (2) are made of sintered zirconia oxide. [4] Sealed watch case according to any one of claims 1 to 3, characterized in that the base (4) comprises an annular peripheral shoulder (8) which receives a seal (10) arranged to be compressed between a first bearing surface (12) of the annular peripheral shoulder (8) and a lower face (14) of the middle part (2). [5] 5. Waterproof watch case according to any one of claims 1 to 4, characterized in that the second peripheral side wall portion (26) of the second element comprises at least two arcuate segments (32) each centered on a point (Ce) offset from the closure axis (O-O), these two sections (32) being connected to each other by a reentrant section (34) to form projections (36), the first peripheral side wall portion (20) of the first element comprising in turn at least two arcuate segments (40) each centered on a point (Cf) offset from the closure axis (O-O ), these two sections (40) being connected to one another by a section (44) whose profile is broken and which defines a clearance (46) of depth such that it allows, in the first angular position, the passage of the projections (36) of the second element in the clearances (46) of the first r element. [6] 6. Sealed watch case according to claim 5, characterized in that each arcuate section (40) of the first element is associated with an arcuate section (32) of the second element, the sections (40; associated with each other having substantially the same radius (Cf; Cc) so that, in the first angular position, each arcuate section (40) of the first element is eccentric relative to the arcuate section (32) of the second element associated therewith, while in the second angular position, each arcuate section (40) of the first element is concentric to the arcuate section (32) of the second element associated therewith. [7] 7. Sealed watch case according to claim 6, characterized in that the peripheral side wall portion of the first and second elements comprises four sections arcuate regularly distributed along the perimeter of the first and second elements. [8] 8. Sealed watch case according to any one of claims 1 to 7, characterized in that the first element is the bottom (4) and the second element is the middle part (2). [9] Sealed watch case according to claim 8, characterized in that the peripheral side wall portion (20) of the bottom (4) is located furthest out from the peripheral side wall portion (26) of the middle part (2).
类似技术:
公开号 | 公开日 | 专利标题 EP1416341B1|2006-05-17|Connection device between a bezel and a watch case EP2859412B1|2021-03-17|Rotating bezel system EP0053543B1|1986-03-12|Devices for fixing objects to sheet metals accessible from one side only EP0604286B1|1996-08-28|Connecting element for two mechanical parts CH621267A5|1981-01-30| EP3237974B1|2018-09-12|Watertight watch case EP0325518B1|1992-03-11|Separable pressure vessel EP0526373B1|1996-03-06|Locked pipe fitting with composite seal assembly EP1033633A1|2000-09-06|Device for the sealed fastening of a glass to a watch case CH710878A2|2016-09-30|waterproof watch case. EP0660203B1|1998-07-22|Watchcase FR2894306A1|2007-06-08|SPHERICAL BEARING ARRANGEMENT. EP0402198A1|1990-12-12|Locking-nut assembly CH641311A|1984-02-29| EP2866100B1|2017-05-24|Seal for a clock piece WO2005015582A1|2005-02-17|Electromagnetic valve, method for attaching a solenoid to said electromagnetic valve, and method for detaching the solenoid from this electromagnetic valve CH706597A2|2013-12-13|Middle part for clock element, has gear angularly interdependent of middle part, and springs angularly interdependent of optical device and support element to allow indexing of position of system with regard to middle part EP2458456A1|2012-05-30|Watch with rigid casing and casing method EP3570116A1|2019-11-20|Clock casing component comprising rotational blocking means BE1012055A3|2000-04-04|Device for fixing nut. EP0955437A2|1999-11-10|Fixing method and device with a ring for panels FR2802234A1|2001-06-15|Safety lock cylinder comprises stator and rotor each with pin sliding in radial housing and anti-lock picking projecting stud on pin which limits sliding between rotor and stator FR2727183A1|1996-05-24|WATERTIGHT RING FR2662474A1|1991-11-29|Dismantleable fast nut FR3007474A1|2014-12-26|BEARING RING.
同族专利:
公开号 | 公开日 CH710878B1|2021-01-15|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题
法律状态:
优先权:
[返回顶部]
申请号 | 申请日 | 专利标题 CH00367/15A|CH710878B1|2015-03-17|2015-03-17|Waterproof watch box.|CH00367/15A| CH710878B1|2015-03-17|2015-03-17|Waterproof watch box.| 相关专利
Sulfonates, polymers, resist compositions and patterning process
Washing machine
Washing machine
Device for fixture finishing and tension adjusting of membrane
Structure for Equipping Band in a Plane Cathode Ray Tube
Process for preparation of 7 alpha-carboxyl 9, 11-epoxy steroids and intermediates useful therein an
国家/地区
|